Topic

Thermal Physics

From microscopic motion and temperature to heat, work, entropy and the limits of thermal machines.

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  • The First Law: Why the Path MattersEnergy conservation becomes thermodynamics when we specify a system boundary and distinguish energy transfer as heat from energy transfer as work. For a closed system with negligible changes in bulk kinetic and gravitational potential energy, use
  • Entropy and Heat Engines: Why Conserved Energy Is Not All UsableThe statistical entropy entry explains why macrostates with many compatible microstates are overwhelmingly favored. Here the aim is operational: calculate entropy changes and use them to decide whether an energy-conserving machine is possible.